2-Chlorooctane → HCID 12790089, 화합물

HRID 1155303

반응식

HRID 1155303 반응식
[Mg].Cl[CH:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH3:4].[CH3:11][CH:12]([Mg]Cl)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH2:21]([Sn:25](Cl)(Cl)Cl)[CH2:22][CH2:23][CH3:24]>C1(C)C(C)=CC=CC=1.O1CCCC1>[CH2:21]([Sn:25]([CH:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH3:4])([CH:12]([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH3:11])[CH:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH3:4])[CH2:22][CH2:23][CH3:24]

참가 물질

7

반응물 4

HCID 123472-ChlorooctaneHCID 14236Butyltin trichlorideHCID 5462224MagnesiumHCID 178443929HCID 178443929, 화합물

생성물 1

HCID 12790089HCID 12790089, 화합물

시약·촉매·용매 2

HCID 7237O-Xylene용매HCID 8028Tetrahydrofuran용매

실험 절차

A 1-liter four-necked flask equipped with a thermometer, a condenser, a stirrer and a dropping funnel was charged with 19.4 g (0.8 mole) of magnesium, 118.9 g (0.8 mole) of 2-chlorooctane and 200 g of tetrahydrofuran, and they were reacted in a stream of nitrogen. To the resulting 2-octyl magnesium chloride solution was added dropwise a solution of 67.7 g (0.24 mole) of mono-n-butyltin trichloride in 200 ml of xylene with stirring at room temperature over the course of 30 minutes. The reaction mixture was reacted for 3 hours at the refluxing temperature, and then subjected to hydrolysis to obtain 120 g of n-butyl tri-2-octyltin having a purity of 98.7%.

후처리

  1. customA 1-liter four-necked flask equipped with a thermometer, a condenser, a stirrer and a dropping funnel
  2. customwere reacted in a stream of nitrogen
  3. customThe reaction mixture was reacted for 3 hours at the refluxing temperature
  4. customsubjected to hydrolysis

출처 및 근거

ORD 기록
ord-4cdc75f395404d33805bdc9bb50f4a64
출처 데이터셋
uspto-grants-1981_11
특허 번호
US04301173

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