Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Carbon Dioxide → Triphenylphosphane dichloride
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Carbon Dioxide | HCID 280 | — |
| 반응물 | Triphenylphosphine Oxide | HCID 13097 | — |
| 반응물 | Oxalyl chloride | HCID 65578 | — |
| 반응물 | HCID 178418416 | HCID 178418416 | — |
| 용매 | Chlorobenzene | HCID 7964 | — |
| 생성물 | Triphenylphosphane dichloride | HCID 13797396 | 200% |
반응 단계
In Example 1, 3.36 g (12 millimoles) of triphenylphosphine oxide and 1.54 g (12 millimoles) of oxalyl chloride were dissolved in 50 ml of monochlorobenzene, and the solution was left standing until the evolution of carbon monoxide and carbon dioxide from the solution was completed. A solution of 12 millimoles of triphenylphosphine dichloride in 50 ml of monochlorobenzene was obtained. That is, the conversion of triphenylphosphine oxide to triphenylphosphine dichloride was effected stoichiometrically.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04301301 |
| 출처 데이터셋 | uspto-grants-1981_11 |
| ORD ID | ord-85e2e41d84d5448dbd7d0bf27f7e2d13 |
| 출처 메모 | uspto-grants-1981_11 |