Carbon Tetrachloride → 2-CHLORO-1-(PHENYLSULFONYL)ETHYL p-BROMOPHENYL SULFIDE

HRID 1156376노트

반응식

HRID 1156376 반응식
[CH:1]([S:3]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)(=[O:5])=[O:4])=[CH2:2].[Br:12][C:13]1[CH:18]=[CH:17][C:16]([S:19]Cl)=[CH:15][CH:14]=1.C(Cl)(Cl)(Cl)[Cl:22]>C(O)(=O)C>[Br:12][C:13]1[CH:18]=[CH:17][C:16]([S:19][CH:1]([S:3]([C:6]2[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=2)(=[O:4])=[O:5])[CH2:2][Cl:22])=[CH:15][CH:14]=1

참가 물질

5

반응물 3

HCID 5943Carbon TetrachlorideHCID 79664Phenyl vinyl sulfoneHCID 11746248Benzenesulfenyl chloride, 4-bromo-

생성물 1

HCID 130447982-CHLORO-1-(PHENYLSULFONYL)ETHYL p-BROMOPHENYL SULFIDE

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

A solution of 24.8 g (0.147 mole) of phenyl vinyl sulfone in 50 ml of carbon tetrachloride and 25 ml of glacial acetic acid at 28° was treated with 32.8 g (0.146 mole) of p-bromobenzenesulfenyl chloride. A 4° exotherm occurred. The reaction mixture was allowed to stand for 72 hours. The solvent was removed by evaporation at reduced pressure. The residue was recrystallized from 50 ml of benzene to give colorless needles, m.p. 97.5°-98.5°.

후처리

  1. customA 4°
  2. customThe solvent was removed by evaporation at reduced pressure
  3. customThe residue was recrystallized from 50 ml of benzene
  4. customto give colorless needles, m.p. 97.5°-98.5°

출처 및 근거

ORD 기록
ord-19000674233748c59ed3c02bd7ac48e6
출처 데이터셋
uspto-grants-1982_06
특허 번호
US04335142

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