Triethylamine → 1-(p-CHLOROPHENYLSULFONYL)VINYL PHENYL SULFIDE

HRID 1156387노트

반응식

HRID 1156387 반응식
[C:1]1([S:7][CH:8]([S:11]([C:14]2[CH:19]=[CH:18][C:17]([Cl:20])=[CH:16][CH:15]=2)(=[O:13])=[O:12])[CH2:9]Cl)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(N(CC)CC)C>O1CCCC1>[C:1]1([S:7][C:8]([S:11]([C:14]2[CH:15]=[CH:16][C:17]([Cl:20])=[CH:18][CH:19]=2)(=[O:13])=[O:12])=[CH2:9])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

참가 물질

4

반응물 2

HCID 8471TriethylamineHCID 130447952-CHLORO-1-(p-CHLOROPHENYLSULFONYL)ETHYL PHENYL SULFIDE

생성물 1

HCID 205359981-(p-CHLOROPHENYLSULFONYL)VINYL PHENYL SULFIDE

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

To a solution of 30 g (86.5 mmoles) of 2-chloro-1-(p-chlorophenylsulfonyl)ethyl phenyl sulfide in 100 ml of tetrahydrofuran was added 12.2 ml (8.88 g, 87.8 mmoles) of triethylamine. After two hours the reaction mixture was filtered to remove triethylamine hydrochloride. The filtrate was evaporated down under reduced pressure, first at 15 mm and finally at 0.01 mm (25° C.), to give a light yellow oil.

후처리

  1. filtrationAfter two hours the reaction mixture was filtered
  2. customto remove triethylamine hydrochloride
  3. customThe filtrate was evaporated down under reduced pressure, first at 15 mm and finally at 0.01 mm (25° C.)
  4. customto give a light yellow oil

출처 및 근거

ORD 기록
ord-f6709858b81d4de18b23bf71e816d299
출처 데이터셋
uspto-grants-1982_06
특허 번호
US04335142

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