Triethylamine → p-BROMOPHENYL 1-(PHENYLSULFONYL)VINYL SULFIDE

HRID 1156388노트

반응식

HRID 1156388 반응식
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH:9]([S:12]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)(=[O:14])=[O:13])[CH2:10]Cl)=[CH:4][CH:3]=1.C(N(CC)CC)C>O1CCCC1.C(OCC)C>[C:15]1([S:12]([C:9]([S:8][C:5]2[CH:4]=[CH:3][C:2]([Br:1])=[CH:7][CH:6]=2)=[CH2:10])(=[O:14])=[O:13])[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1

참가 물질

5

반응물 2

HCID 8471TriethylamineHCID 130447982-CHLORO-1-(PHENYLSULFONYL)ETHYL p-BROMOPHENYL SULFIDE

생성물 1

HCID 13044810p-BROMOPHENYL 1-(PHENYLSULFONYL)VINYL SULFIDE

시약·촉매·용매 2

HCID 3283Diethyl Ether용매HCID 8028Tetrahydrofuran용매

실험 절차

A solution of 10.2 g (26.1 mmoles) of 2-chloro-1-(phenylsulfonyl)ethyl p-bromophenyl sulfide in 50 ml of tetrahydrofuran was diluted with 50 ml of diethyl ether and treated with 3.63 ml (2.65 g, 26.2 mmoles) of triethylamine. After 20 minutes the triethylamine hydrochloride was removed by filtration. The filtrate was freed of solvent by evaporation under reduced pressure to leave a viscous, pale yellow oil of n20 1.6338.

후처리

  1. customAfter 20 minutes the triethylamine hydrochloride was removed by filtration
  2. customThe filtrate was freed of solvent by evaporation under reduced pressure
  3. customto leave a viscous, pale yellow oil of n20 1.6338

출처 및 근거

ORD 기록
ord-ed20170bc6fc4bc284c0ff987a8d92c0
출처 데이터셋
uspto-grants-1982_06
특허 번호
US04335142

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