Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Pempidine → Ethyl 3-phenylprop-2-enoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Pempidine | HCID 6603 | — |
| 반응물 | Trioctylamine | HCID 14227 | — |
| 반응물 | N-Ethyldicyclohexylamine | HCID 23563 | — |
| 반응물 | Diisopropylethylamine | HCID 81531 | — |
| 반응물 | Tri(2-ethylhexyl)amine | HCID 102705 | — |
| 반응물 | Lithium acetate | HCID 3474584 | — |
| 반응물 | Benzyltrimethylammonium acetate | HCID 13086341 | — |
| 용매 | Triethylamine | HCID 8471 | — |
| 생성물 | Ethyl 3-phenylprop-2-enoate | HCID 7649 | — |
반응 단계
The procedure described in Example 1 is repeated, except that 0.03125 mol of one of the bases tri-n-octylamine, tris-(2-ethylhexyl)-amine, ethyl-dicyclohexylamine, triethylamine, ethyl-diisopropylamine, N-methyl-2,2,6,6-tetramethylpiperidine, lithium acetate and trimethyl-benzylammonium acetate is used in place of 0.03125 mol of tri-n-butylamine. After working up as described in Example 1, ethyl cinnamate is obtained in comparably good yields.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04335054 |
| 출처 데이터셋 | uspto-grants-1982_06 |
| ORD ID | ord-e511e4f9f090421ca5ee66ff077b40fb |
| 출처 메모 | uspto-grants-1982_06 |