Methyl phenoxyacetate → p-Methoxycarbonylmethoxyphenyltellurium trichloride

HRID 1164689노트

반응식

HRID 1164689 반응식
[Te:1]([Cl:5])(Cl)([Cl:3])[Cl:2].[CH3:6][O:7][C:8]([CH2:10][O:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[O:9]>C(Cl)(Cl)(Cl)Cl>[CH3:6][O:7][C:8]([CH2:10][O:11][C:12]1[CH:17]=[CH:16][C:15]([Te:1]([Cl:5])([Cl:3])[Cl:2])=[CH:14][CH:13]=1)=[O:9]

참가 물질

4

반응물 2

HCID 16365Methyl phenoxyacetateHCID 61443Tellurium tetrachloride

생성물 1

HCID 12688223p-Methoxycarbonylmethoxyphenyltellurium trichloride수율 96.1%

시약·촉매·용매 1

HCID 5943Carbon Tetrachloride용매

실험 절차

Tellurium tetrachloride (11.36 g, 0.042 mol) and methyl phenoxy acetate (21.00 g, 0.127 mol) were refluxed in carbon tetrachloride (175 ml) for 18 h. The reaction solution was filtered while still hot, the filtrate cooled in an ice bath and the resulting solid filtered to afford p-methoxycarbonylmethoxyphenyltellurium trichloride (16.11 g, 96%) δ(CDCl3 /DMSO d6) 8.38 (2H,d,9Hz), 6.90 (2H,d,9 Hz), 4.67 (2H,s), and 3.77 (3H,s). No attempt was made to purify this compound and it was used directly in the next step.

후처리

  1. filtrationThe reaction solution was filtered while still hot, the filtrate
  2. temperaturecooled in an ice bath
  3. filtrationthe resulting solid filtered

출처 및 근거

ORD 기록
ord-802221c9259d47beac66e923a9c93f66
출처 데이터셋
uspto-grants-1983_01
특허 번호
US04370497

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