Hexane → 11H-Benzo(a)carbazole, 11-methyl-

반응식

[CH:1]1[C:6]2=[C:7]3[C:15](=[CH:16][CH:17]=[C:5]2[CH:4]=[CH:3][CH:2]=1)[C:14]1[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=1)[NH:8]3.[CH3:18]CCCCC>>[CH3:18][N:8]1[C:7]2[C:15](=[CH:16][CH:17]=[C:5]3[CH:4]=[CH:3][CH:2]=[CH:1][C:6]3=2)[C:14]2[C:9]1=[CH:10][CH:11]=[CH:12][CH:13]=2

참가 물질

반응물 2

HCID 8058Hexane

HCID 9196Benzo[a]carbazole

생성물 1

HCID 8316311H-Benzo(a)carbazole, 11-methyl-수율 97.3%

실험 절차

Using the procedure outlined in Example 34A, 11H-benzo[a]carbazole (Cambridge Chemicals, Inc.) gave a 97.3% yield of 11-methyl-11H-benzo[a]carbazole, mp 167°-169°, (hexane), (C,H,N).

출처 및 근거

ORD 기록: ord-3e3bfb033b274b4fb8204946502341ed
출처 데이터셋: uspto-grants-1990_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04910218

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