Diethylamine → 1-Methoxycarbonyl-7-isopropylazulene

HRID 1165893노트

반응식

HRID 1165893 반응식
[CH3:1][O:2][C:3]([C:5]1[C:9](=O)O[C:7]2=[CH:11][CH:12]=[CH:13][C:14]([CH:16]([CH3:18])[CH3:17])=[CH:15][C:6]=12)=[O:4].[CH2:19](NCC)C>>[CH3:1][O:2][C:3]([C:5]1[C:6]2[C:7]([CH:11]=[CH:12][CH:13]=[C:14]([CH:16]([CH3:18])[CH3:17])[CH:15]=2)=[CH:19][CH:9]=1)=[O:4]

참가 물질

3

반응물 2

HCID 8021DiethylamineHCID 100604625-Isopropyl-3-(methoxycarbonyl)-2H-cyclohepta(b)furan-2-one

생성물 1

HCID 111388961-Methoxycarbonyl-7-isopropylazulene

실험 절차

To a diethylamine (120 ml) suspension of 3-methoxycarbonyl-5-isopropyl-2H-cyclohepta[b]furan-2-one (16) (5.0 g) acetaldehyde (5.7 ml) was added.

후처리

  1. additionwas added

출처 및 근거

ORD 기록
ord-fcc09138ede142aa9313dea99ba36158
출처 데이터셋
uspto-grants-1990_03
특허 번호
US04912134

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