Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methyl p-toluenesulfonate → Bis(4-tert-butylphenyl)iodonium p-toluenesulfonate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methyl p-toluenesulfonate | HCID 6645 | — |
| 반응물 | Iodonium, bis[4-(1,1-dimethylethyl)phenyl]-, chloride | HCID 21889439 | — |
| 용매 | tert-Butyl methyl ether | HCID 15413 | — |
| 생성물 | Bis(4-tert-butylphenyl)iodonium p-toluenesulfonate | HCID 16216932 | 91% |
반응 단계
Bis(p-tert-butylphenyl)iodonium chloride (428.8 g; 1.0 mol) and methyl p-toluenesulfonate (223.5 g; 1.2 mol) were suspended in t-butyl methyl ether (500 ml). The suspension was heated at 55° C.-58° C. and refluxed for 5 hours while being stirred. After the reaction mixture had been cooled, formed white solid was separated through filtration. The white solid was washed with t-butyl methyl ether and dried under vacuum, to thereby yield 513.7 g of bis(p-tert-butylphenyl)iodonium p-toluenesulfonate (yield: 91%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06620957B1 |
| 출처 데이터셋 | uspto-grants-2003_09 |
| ORD ID | ord-8be9658a64274639885547c8d9585bde |
| 출처 메모 | uspto-grants-2003_09 |