Trimethyl Phosphate → HCID 178502937, 화합물

HRID 1168025

반응식

HRID 1168025 반응식
[I-].[C:2]1([S+:8]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[P:21](OC)([O:25][CH3:26])([O:23][CH3:24])=[O:22]>>[CH3:24][O:23][PH:21](=[O:22])[O:25][CH3:26].[C:15]1([S+:8]([C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1

참가 물질

3

반응물 2

HCID 10541Trimethyl PhosphateHCID 21881071Triphenylsulfonium iodide

생성물 1

HCID 178502937HCID 178502937, 화합물수율 75%

반응 조건

온도
130 °C

실험 절차

A mixture of triphenylsulfonium iodide (390 mg; 1 mmol) and trimethyl phosphate (1 g) was stirred at 130° C. for 3 hours. Subsequently, the homogenous solution was cooled, and the thus-obtained solid matter was washed with IPA, to thereby yield 280 mg of the target compound as white crystals (yield: 72.2%). The anion content of the resultant compound was determined by ion chromatography. The iodide anion content was determined to be not greater than 50 ppm.

후처리

  1. temperatureSubsequently, the homogenous solution was cooled
  2. washthe thus-obtained solid matter was washed with IPA

출처 및 근거

ORD 기록
ord-3e2c4f206b8748ee8d145081cbc59692
출처 데이터셋
uspto-grants-2003_09
특허 번호
US06620957B1

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