4,4'-Dibromostilbene → 4,4'-bis[N-(dibenzofuran-2-yl)-N-phenylamino]stilbene

HRID 1183196

반응식

HRID 1183196 반응식
Br[C:2]1[CH:7]=[CH:6][C:5]([CH:8]=[CH:9][C:10]2[CH:15]=[CH:14][C:13](Br)=[CH:12][CH:11]=2)=[CH:4][CH:3]=1.[CH:17]1[C:25]2[C:24]3[CH:26]=[CH:27][CH:28]=[CH:29][C:23]=3[O:22][C:21]=2[CH:20]=[CH:19][C:18]=1[NH:30][C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=1>C(OCC)(=O)C.CCCCCC>[CH:17]1[C:25]2[C:24]3[CH:26]=[CH:27][CH:28]=[CH:29][C:23]=3[O:22][C:21]=2[CH:20]=[CH:19][C:18]=1[N:30]([C:2]1[CH:7]=[CH:6][C:5]([CH:8]=[CH:9][C:10]2[CH:15]=[CH:14][C:13]([N:30]([C:31]3[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=3)[C:18]3[CH:19]=[CH:20][C:21]4[O:22][C:23]5[CH:29]=[CH:28][CH:27]=[CH:26][C:24]=5[C:25]=4[CH:17]=3)=[CH:12][CH:11]=2)=[CH:4][CH:3]=1)[C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=1

참가 물질

4

반응물 2

HCID 533959814,4'-DibromostilbeneHCID 67204676N-phenyl-2-Dibenzofuranamine

생성물 1

HCID 681097244,4'-bis[N-(dibenzofuran-2-yl)-N-phenylamino]stilbene

시약·촉매·용매 1

HCID 21226206Ethyl acetate hexane용매

실험 절차

The Rf values of the object of the synthesis, 4,4′-dibromostilbene, and (dibenzofuran-2-yl)-phenylamine were respectively 0.37, 0.62, and 0.31, which were found by silica gel thin layer chromatography (TLC) (ethyl acetate:hexane (1:10) as the developing solvent).

출처 및 근거

ORD 기록
ord-fb94fe00aaea462a81b4c37cff3a3e99
출처 데이터셋
uspto-grants-2014_03
특허 번호
US08664263B2

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