Phenyltrimethylammonium bromide dibromide → HCID 58545558, 화합물
반응식
[S:1]1[C:5]([C:6](=[O:8])[CH3:7])=[CH:4][CH:3]2[S:9][CH:10]=[CH:11][CH:2]12.[Br-:12].[Br-].[Br-].C1([N+](C)(C)C)C=CC=CC=1.C1([N+](C)(C)C)C=CC=CC=1.C1([N+](C)(C)C)C=CC=CC=1>C1COCC1>[Br:12][CH2:7][C:6]([C:5]1[S:1][CH:2]2[CH:11]=[CH:10][S:9][CH:3]2[CH:4]=1)=[O:8]참가 물질
4
실험 절차
1-(3a,6a-Dihydro-thieno[3,2-b]thiophen-2-yl)-ethanone (453 mg, 2.48 mmol) was dissolved in THF (12 mL) and phenyltrimethylammonium tribromide (932 mg, 2.48 mmol) was added. After stirring for 1 h, the suspension was filtered over CELITE. The filtrate was diluted with diethyl ether, then washed with saturated aqueous NaHCO3 and brine then dried over MgSO4, filtered and concentrated to afford the title compound which was carried on without purification.
후처리
- filtrationthe suspension was filtered over CELITE
- additionThe filtrate was diluted with diethyl ether
- washwashed with saturated aqueous NaHCO3 and brine
- dry with materialthen dried over MgSO4
- filtrationfiltered
- concentrationconcentrated
출처 및 근거
- ORD 기록
- ord-0ef13626e81642ab80c59f10b1fee5c8
- 출처 데이터셋
- uspto-grants-2014_03
- 특허 번호
- US08669234B2
반응 노트
불러오는 중…