tert-Butyl (4-aminophenyl)carbamate → HCID 86690018, 화합물

반응식

O([C:9]1[CH:18]=[CH:17][C:16]2[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=2)[C:10]=1[N+:19]([O-:21])=[O:20])S(C(F)(F)F)(=O)=O.[NH2:22][C:23]1[CH:28]=[CH:27][C:26]([NH:29][C:30](=[O:36])[O:31][C:32]([CH3:35])([CH3:34])[CH3:33])=[CH:25][CH:24]=1>>[N+:19]([C:10]1[C:11]2[C:16](=[CH:15][CH:14]=[CH:13][CH:12]=2)[CH:17]=[CH:18][C:9]=1[NH:22][C:23]1[CH:24]=[CH:25][C:26]([NH:29][C:30]([O:31][C:32]([CH3:35])([CH3:34])[CH3:33])=[O:36])=[CH:27][CH:28]=1)([O-:21])=[O:20]

참가 물질

반응물 2

HCID 688611tert-Butyl (4-aminophenyl)carbamate

HCID 147652731-Nitronaphthalen-2-yl triflate

생성물 1

HCID 86690018HCID 86690018, 화합물수율 81%

실험 절차

1-Nitronaphthalen-2-yl triflate (2.50 g, 7.78 mmol) and tert-butyl 4-aminophenylcarbamate (1.62 g, 7.78 mmol) were used in a process similar to Example 1(1) to give the titled compound (2.39 g, yield 81%).

출처 및 근거

ORD 기록: ord-513abf23cc88498eb7b6c73a58df13dd
출처 데이터셋: uspto-grants-2014_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08673915B2

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