1-Amino-2-propanol → Tbpa mipa

반응식

[CH3:1][CH2:2][CH2:3][CH2:4][O:5][P:6]([O:13][CH2:14][CH2:15][CH2:16][CH3:17])([O:8][CH2:9][CH2:10][CH2:11][CH3:12])=[O:7].[CH3:18][CH:19]([OH:22])[CH2:20][NH2:21]>>[CH3:12][CH2:11][CH2:10][CH2:9][O:8][P:6]([O:5][CH2:4][CH2:3][CH2:2][CH3:1])([O:13][CH2:14][CH2:15][CH2:16][CH3:17])=[O:7].[CH3:18][CH:19]([OH:22])[CH2:20][NH2:21]

참가 물질

반응물 2

HCID 41-Amino-2-propanol

HCID 31357Tributyl Phosphate

생성물 1

HCID 131731251Tbpa mipa

실험 절차

Reaction of TBPA with MIPA gives an TBPA/MIPA adduct. TBPA is sold in commerce by Albermarle as Saytex® RB-49. MIPA is sold in commerce by Dow Chemical. 44.8 mmol of TBPA is added to a round bottom flask with 50.74 grams of ethanol. The mixture is heated to reflux after which 44.8 mmol of MIPA is added dropwise and the solution refluxed for 1 hour. The ethanol is removed using a rotary evaporator to produce a yellow crystalline solid.

출처 및 근거

ORD 기록: ord-d6ca116be7344af0ad32793e54d9c541
출처 데이터셋: uspto-grants-2014_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08679990B2

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