Tetrahydrofuran → HCID 131731270, 화합물

HRID 1192852노트

반응식

HRID 1192852 반응식
[I-:1].[La+3:2].[I-].[I-].[C:5]([C:9]1[N-:10][C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])=[C:12]([C:14]([CH3:18])([CH3:17])[CH2:15][CH3:16])[N:13]=1)([CH3:8])([CH3:7])[CH3:6].[K+].[CH2:25]1[CH2:29][O:28][CH2:27][CH2:26]1>>[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[I-:1].[I-:1].[C:5]([C:9]1[N-:13][C:12]([C:14]([CH3:17])([CH3:18])[CH2:15][CH3:16])=[C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])[N:10]=1)([CH3:8])([CH3:7])[CH3:6].[La+3:2]

참가 물질

4

반응물 3

HCID 8028TetrahydrofuranHCID 25210651LANTHANUM IODIDEHCID 131731268HCID 131731268, 화합물

생성물 1

HCID 131731270HCID 131731270, 화합물

실험 절차

Lanthanum (III) iodide (1.0 g, 0.002 mol) was stirred in 50 mL of THF for 30 mins at room temperature. Potassium 2-tert-butyl-4,5-di-(1,1-dimethylpropyl)imidazolate (0.6 g, 0.002 mol) was added, and the resulting mixture was refluxed for 60 hours. THF was removed by vacuum, followed by hexane extraction, then filtration. The hexane was removed by vacuum, and the resulting solid was crystallized to isolate the final product.

후처리

  1. temperaturethe resulting mixture was refluxed for 60 hours
  2. customTHF was removed by vacuum
  3. extractionfollowed by hexane extraction
  4. filtrationfiltration
  5. customThe hexane was removed by vacuum
  6. customthe resulting solid was crystallized

출처 및 근거

ORD 기록
ord-cce2f2d0864142b2a49bae8972b66b50
출처 데이터셋
uspto-grants-2014_03
특허 번호
US08680289B2

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