Nitromethane → (E)-6-nitrohex-5-enal

HRID 1193013

반응식

HRID 1193013 반응식
[N+:1]([CH3:4])([O-:3])=[O:2].C[O:6][CH:7](OC)[CH2:8][CH2:9][CH2:10][CH:11]=O>CCOC(C)=O.CCCCCC>[N+:1](/[CH:4]=[CH:11]/[CH2:10][CH2:9][CH2:8][CH:7]=[O:6])([O-:3])=[O:2]

참가 물질

4

반응물 2

HCID 6375NitromethaneHCID 170903Pentanal, 5,5-dimethoxy-

생성물 1

HCID 57516560(E)-6-nitrohex-5-enal수율 66%

시약·촉매·용매 1

HCID 21226206Ethyl acetate hexane용매

실험 절차

Prepared according to the general procedure A from nitromethane 112a (80 mmol) and 5,5-dimethoxypentanal 131 (16 mmol) to provide the title compound as yellow oil (1.51 g, 66% yield) after silica gel chromatography (EtOAc/Hexane).

후처리

  1. customPrepared

출처 및 근거

ORD 기록
ord-4a9714f50b60466a8e0da7bc31c3558b
출처 데이터셋
uspto-grants-2014_03
특허 번호
US08680335B2

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