Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
6-Ethylchrysene → 12-Ethyl-6-chrysenecarbaldehyde
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 6-Ethylchrysene | HCID 75951 | — |
| 반응물 | 6-Chrysenecarbaldehyde | HCID 12438774 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 12-Ethyl-6-chrysenecarbaldehyde | HCID 13375390 | 76% |
반응 단계
6-Ethylchrysene (Cambridge Chemical, Inc., 60 g, 0.234 mol) was formylated according to the procedure outlined in 1A, except that CH2Cl2 (1 L) was used as the reaction solvent. The crude material was chromatographed on a plug of SiO2 (1 kg) using PhCH3 as the eluting solvent, afforded 50.38 g (76%) of 12-ethyl-6-chrysenecarbaldehyde mp 138°-139°, (C, H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04810727 |
| 출처 데이터셋 | uspto-grants-1989_03 |
| ORD ID | ord-9ec06c3fc0c14f46bcea6fa7f914ba6a |
| 출처 메모 | uspto-grants-1989_03 |