Benzene → Acetophenone

HRID 1195125노트

반응식

HRID 1195125 반응식
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:7](Cl)(=[O:9])[CH3:8]>[O-]S(C(F)(F)F)(=O)=O.[Ga+3].[O-]S(C(F)(F)F)(=O)=O.[O-]S(C(F)(F)F)(=O)=O>[C:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)(=[O:9])[CH3:8]

참가 물질

4

반응물 2

HCID 241BenzeneHCID 6367Acetyl chloride

생성물 1

HCID 7410Acetophenone

시약·촉매·용매 1

HCID 2733940GALLIUM(III) TRIFLUOROMETHANESULFONATE촉매

실험 절차

Benzene (1 equivalent) was reacted with acetyl chloride (0.5 equivalents) in the presence of 0.25 equivalents of gallium triflate catalyst at 50°-60° C. for 1 hour giving 0.35 equivalents of acetophenone.

출처 및 근거

ORD 기록
ord-4e7b144998634d1d9a7db8ba8f8abb01
출처 데이터셋
uspto-grants-1992_05
특허 번호
US05110778

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