Dicyclohexylcarbodiimide → 4-(1-Methylheptyloxycarbonyl)phenyl 4'-n-Nonanoyloxybiphenyl-4-carboxylate

HRID 1196794

반응식

HRID 1196794 반응식
[C:1]([O:11][C:12]1[CH:17]=[CH:16][C:15]([C:18]2[CH:23]=[CH:22][C:21]([C:24]([OH:26])=[O:25])=[CH:20][CH:19]=2)=[CH:14][CH:13]=1)(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].O[C:28]1[CH:44]=[CH:43][C:31]([C:32]([O:34][CH:35]([CH3:42])[CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41])=[O:33])=[CH:30][CH:29]=1.C1CCC(N=C=NC2CCCCC2)CC1.CN(C1C=CC=CN=1)C>O1CCCC1>[C:1]([O:11][C:12]1[CH:13]=[CH:14][C:15]([C:18]2[CH:23]=[CH:22][C:21]([C:24]([O:26][C:28]3[CH:44]=[CH:43][C:31]([C:32]([O:34][CH:35]([CH3:42])[CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41])=[O:33])=[CH:30][CH:29]=3)=[O:25])=[CH:20][CH:19]=2)=[CH:16][CH:17]=1)(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

참가 물질

6

반응물 4

HCID 10868DicyclohexylcarbodiimideHCID 218852-DimethylaminopyridineHCID 110103794-(1-Methylheptyloxycarbonyl)phenol2회HCID 136684514'-Nonanoyloxybiphenyl-4-carboxylic acid

생성물 1

HCID 159192774-(1-Methylheptyloxycarbonyl)phenyl 4'-n-Nonanoyloxybiphenyl-4-carboxylate

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

In 330 ml of dehydrated tetrahydrofuran were dissolved 5.00 g of 4'-nonanoyloxybiphenyl-4-carboxylic acid and 6.76 g of 1-methylheptyl 4-hydroxybenzoate synthesized in (2) above. To the solution were added 6.18 g of DCC and 0.24 g of dimethylaminopyridine, followed by stirring for one day at room temperature.

출처 및 근거

ORD 기록
ord-bf99518655ed4455b7ae0f2d46f54000
출처 데이터셋
uspto-grants-1992_05
특허 번호
US05116531

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