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1-Chloro-4-nitrobenzene → HCID 178507292, 화합물

HRID 1197401
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HRID 1197401 반응식
[NH2:1][C:2]1[S:3][C:4]([NH2:7])=[CH:5][CH:6]=1.[N+:8]([C:11]1[CH:16]=[CH:15][C:14](Cl)=[CH:13][CH:12]=1)([O-:10])=[O:9].C(=O)([O-])[O-].[K+].[K+]>[Cu].CN(C)C=O>[N+:8]([C:11]1[CH:16]=[CH:15][C:14]([C:6]2[CH:5]=[C:4]([NH2:7])[SH:3]([C:14]3[CH:15]=[CH:16][C:11]([N+:8]([O-:10])=[O:9])=[CH:12][CH:13]=3)([C:14]3[CH:15]=[CH:16][C:11]([N+:8]([O-:10])=[O:9])=[CH:12][CH:13]=3)([C:14]3[CH:15]=[CH:16][C:11]([N+:8]([O-:10])=[O:9])=[CH:12][CH:13]=3)[C:2]=2[NH2:1])=[CH:13][CH:12]=1)([O-:10])=[O:9]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 3

HCID 74741-Chloro-4-nitrobenzeneHCID 11430Potassium CarbonateHCID 19599071Thiophene-2,5-diamine

생성물 1

HCID 178507292HCID 178507292, 화합물

시약·촉매·용매 2

HCID 23978Copper촉매HCID 6228Dimethylformamide용매

실험 절차

In 600 parts of dimethylformamide, 0.5 mol (60 parts) of 2,5-diaminothiophene, 2.3 mol (360 parts) of p-nitrochlorobenzene, 1.2 mol (170 parts) of anhydrous potassium carbonate and 10 parts of copper powder were refluxed with stirring for 4 days. After the reaction was completed, the reaction mixture was filtered, and the residue was thoroughly washed with dimethylformamide, water and acetone, and then dried. Thus, 105 parts of reddish brown tetrakis(p-nitrophenyl)-2,5-diaminothiophene was obtained.

후처리

  1. filtrationthe reaction mixture was filtered
  2. washthe residue was thoroughly washed with dimethylformamide, water and acetone
  3. customdried

출처 및 근거

ORD 기록
ord-eb3176188d074544b1de8a676f3e6622
출처 데이터셋
uspto-grants-1994_01
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US05275925

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