참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 4-Chlorostyrene | HCID 14085 | — |
| 반응물 | Magnesium | HCID 5462224 | — |
| 반응물 | Chloro(dimethyl)[(propan-2-yl)oxy]silane | HCID 13033739 | — |
| 반응물 | HCID 178436504 | HCID 178436504 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 1-[Dimethyl(1-methylethoxy)silyl]-4-ethenylbenzene | HCID 18961613 | 45% |
반응 단계
A solution of isopropoxydimethylchlorosilane (15.2 g, 100 mmole) in dry THF (50 mL) was added dropwise over a 1 hour period to a solution of (4-vinylphenyl)magnesium chloride, prepared from 4-vinylphenyl chloride (13.85 g, 100 mmole) and magnesium (3.0 g, 125 mmole) in dry 100 mL THF. The temperature was maintained at 10° C. during the addition. The reaction mixture was stirred at room temperature for over 18 hours. The desired product distilling at 45°-49° C./0.2 mm was obtained in 45% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05278244 |
|---|
| 출처 데이터셋 | uspto-grants-1994_01 |
|---|
| ORD ID | ord-03f27159cd4f48c8bc89eff936c386cd |
|---|
| 출처 메모 | uspto-grants-1994_01 |
|---|
