Triethoxychlorosilane → Acryltriethoxysilane

HRID 11980

반응식

HRID 11980 반응식
[C:1]([O-:5])(=O)[CH:2]=[CH2:3].[Na+].Cl[Si:8]([O:15][CH2:16][CH3:17])([O:12][CH2:13][CH3:14])[O:9][CH2:10][CH3:11]>C1COCC1>[C:1]([Si:8]([O:15][CH2:16][CH3:17])([O:12][CH2:13][CH3:14])[O:9][CH2:10][CH3:11])([CH:2]=[CH2:3])=[O:5]

참가 물질

4

반응물 2

HCID 78398TriethoxychlorosilaneHCID 4068533Sodium acrylate

생성물 1

HCID 21864273Acryltriethoxysilane

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매2회

반응 조건

온도
-70 °C

실험 절차

6.123 g (0.0651 mol) sodium acrylate is dissolved to 25 mL THF and cooled to −70° C. 12.8 mL (0.0651 mol, 12.938 g) chlorotriethoxysilane in THF (15 mL) is added dropwise to reaction solution. The solution is stirred for over night allowing it to warm up to room temperature. NaCl is removed by filtration and solution evaporated to dryness to result clear liquid, acryltriethoxysilane.

후처리

  1. temperatureto warm up to room temperature
  2. customNaCl is removed by filtration and solution
  3. customevaporated to dryness

출처 및 근거

ORD 기록
ord-ebe86df30b2441388fb356c07f9e4914
출처 데이터셋
uspto-grants-2006_08
특허 번호
US07098346B2

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