Sodium Laurate → Trimethylammonium acetonitrile laurate

HRID 1198375

반응식

HRID 1198375 반응식
[Cl-].[C:2](#[N:4])[CH3:3].[CH3:5][NH+:6]([CH3:8])[CH3:7].[C:9]([O-:22])(=[O:21])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[Na+].C([O-])(=O)CCCCCCCCCCC>CO>[C:9]([O-:22])(=[O:21])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[C:2](#[N:4])[CH3:3].[CH3:5][NH+:6]([CH3:8])[CH3:7]

참가 물질

5

반응물 3

HCID 2735067Sodium LaurateHCID 4149208DodecanoateHCID 86747519HCID 86747519, 화합물

생성물 1

HCID 19102381Trimethylammonium acetonitrile laurate수율 93%

시약·촉매·용매 1

HCID 887Methanol용매2회

실험 절차

Trimethylammonium acetonitrile chloride (1.0 g, 0.007435 mole) was dissolved in methanol (20 ml) in a test tube. Sodium laurate (1.65 g, 0.007435 mole) was dissolved in boiling methanol (50 ml) and the two solutions mixed. The solution was evaporated to dryness and the solid heated with ethanol (60 ml). A granular precipitate of sodium chloride settled out and was filtered off, but less than the theorectical amount was obtained. The ethanolic solution was evaporated to dryness, azeotroped twice with IPA to give a lumpy solid containing white and fawn components (2.08 g, yield 93%). 'H NMR (σ, D2O) 0.85 (t, 3H, CH3-) 1.3 (s, I6H, CH3 -(CH2)8), 1.55 (m, 2H, CH2CH2CO-) 3.4 (s, 9H, (CH3)3N+) ppm. The ratio of quat to laurate was 1.3:1.

후처리

  1. additionthe two solutions mixed
  2. customThe solution was evaporated to dryness
  3. temperaturethe solid heated with ethanol (60 ml)
  4. filtrationwas filtered off
  5. customless than the theorectical amount was obtained
  6. customThe ethanolic solution was evaporated to dryness
  7. customazeotroped twice with IPA
  8. customto give a lumpy solid
  9. additioncontaining white

출처 및 근거

ORD 기록
ord-dbc5b480494c4541a91a422562b60c2b
출처 데이터셋
uspto-grants-1994_01
특허 번호
US05281361

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