Acetyl chloride → 4,4-Dinitrobutyl acetate

HRID 1199508노트

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HRID 1199508 반응식
[N+:1]([CH:4]([N+:9]([O-:11])=[O:10])[CH2:5][CH2:6][CH2:7][OH:8])([O-:3])=[O:2].[C:12](Cl)(=[O:14])[CH3:13]>C(Cl)Cl>[C:12]([O:8][CH2:7][CH2:6][CH2:5][CH:4]([N+:9]([O-:11])=[O:10])[N+:1]([O-:3])=[O:2])(=[O:14])[CH3:13]

참가 물질

4

반응물 2

HCID 6367Acetyl chlorideHCID 144017664,4-Dinitrobutan-1-ol

생성물 1

HCID 144017674,4-Dinitrobutyl acetate

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

This ester was synthesized by treating a solution of 4,4-dinitro-1-butanol (39.2 g, 0.24 mols) in CH2Cl2 (100 ml) with acetyl chloride (22 ml, 24 g, 0.31 mol). After 90 minutes at room temperature, the reaction was quenched with ice water. Separation, drying (MgSO4), and concentration of the organic phase gave the product (42.7 g, 87%) as a light yellow oil; nD =1.4574 (24C). The infrared spectrum of the product had peaks at 2960, 1745, 1575, 1245, and 1060 cm-1. Elemental analyses-Calculated for C6H10N2O6 : C, 34.95; H, 4.85; N, 13.59; Found: C, 35.17; H, 4.83; N, 12.95.

후처리

  1. customthe reaction was quenched with ice water
  2. customSeparation
  3. dry with materialdrying (MgSO4), and concentration of the organic phase

출처 및 근거

ORD 기록
ord-cf1ae0a1194d4a8491da65d770a89a86
출처 데이터셋
uspto-grants-1990_02
특허 번호
US04900851

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