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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 1199630생성일: 2026년 10월 26일

Chromium → Chromic nitrate

https://huagongshe.com/reaction/1199630

반응식

참여 물질

역할이름HCID투입량
반응물ChromiumHCID 23976—
반응물Chromic nitrateHCID 24598—
반응물Cobalt, compd. with nickel (1:1)HCID 10261079—
생성물Chromic nitrateHCID 24598—
생성물Nickel-cobalt-chromium oxideHCID 131716318—

반응 조건

온도470 °C

반응 단계

62.5 g of carboxymethyl cellulose was added to 2.5 liters of distilled water and the mixture was kneaded and deaerated to obtain a binder solution. To this binder solution was added 2.5 kg of nickel powder of about 3 μm in average particle size and the mixture was further kneaded and deaerated to obtain a slurry. A wire gauze of 40 meshes was passed through this slurry solution to deposit the slurry thereon and then this wire gauze was passed through a slit to adjust thickness and dried. Thereafter, the wire gauze was sintered at 850° C. in a hydrogen atmosphere to obtain a nickel porous sintered body. Then, an aqueous cobalt nitrate solution was prepared so that addition amount of cobalt based on nickel was 5 atom %. The above nickel porous sintered body was dipped in this aqueous cobalt nitrate solution for 15 minutes and then, was taken out, followed by removing an excess solution and drying. This was sintered at 700° C. in a hydrogen atmosphere to obtain a nickel-cobalt porous sintered body. Another aqueous chromium nitrate solution was prepared so that addition amount of chromium based on nickel was 7 atom %. The above nickel-cobalt porous sintered body was dipped in this aqueous chromium nitrate solution for 15 minutes. Then, this was taken out, followed by removing an excess solution and drying. Thereafter, this was heated at 470° C. in an air atmosphere to oxidize chromium and then was further heated to 700° C. in a hydrogen atmosphere to obtain a nickel-cobalt-chromium oxide ternary anode. Performance of a cell which had the anode obtained in this Example is shown by curve E in FIG. 2. The results were similar to those for the cell where the anode obtained in Example 1 was used.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US04902587
출처 데이터셋uspto-grants-1990_02
ORD IDord-19e8ad1e2ca8460ca8396f93c67a819f
출처 메모uspto-grants-1990_02