Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydrogen Sulfide → 4,6-Dimethylpyrimidin-2-ylthiourea
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydrogen Sulfide | HCID 402 | — |
| 반응물 | Dichloromethane | HCID 6344 | — |
| 반응물 | (4,6-Dimethylpyrimidin-2-yl)cyanamide | HCID 521618 | — |
| 용매 | Pyridine | HCID 1049 | — |
| 생성물 | 4,6-Dimethylpyrimidin-2-ylthiourea | HCID 747500 | — |
반응 단계
A suspension of 10 g of 2-cyanoamino-4,6-dimethylpyrimidine in 50 ml of pyridine was saturated with hydrogen sulfide and stored for 1 hour at 25°. The H2S treatment was repeated twice more, and the mixture was allowed to stir at 25° for 16 hours. Methylene chloride was added, and the product was filtered and washed with methylene chloride to afford 8 g of 4,6-dimethylpyrimidin-2-yl thiourea, m.p. >260°. IR (Nujol) 3280, 3180, 3120, 1610 cm-1.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04904299 |
| 출처 데이터셋 | uspto-grants-1990_02 |
| ORD ID | ord-96f5c4c8ef3842fb955baf33b021b241 |
| 출처 메모 | uspto-grants-1990_02 |