HCID 14650456, 화합물 → HCID 14650449, 화합물

HRID 1200193노트

반응식

HRID 1200193 반응식
[C:1]1([C:7]2[O:8][C:9]3[C:17]([CH2:18][C:19]([O:21]CC)=[O:20])=[CH:16][CH:15]=[CH:14][C:10]=3[C:11](=[O:13])[CH:12]=2)[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1>C(O)(=O)C.O>[C:1]1([C:7]2[O:8][C:9]3[C:17]([CH2:18][C:19]([OH:21])=[O:20])=[CH:16][CH:15]=[CH:14][C:10]=3[C:11](=[O:13])[CH:12]=2)[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1

참가 물질

4

반응물 1

HCID 14650456HCID 14650456, 화합물

생성물 1

HCID 14650449HCID 14650449, 화합물수율 68%

시약·촉매·용매 2

HCID 176Acetic Acid용매HCID 962Water용매

실험 절차

Ethyl [2-(1-cyclohexenyl)-4-oxo-4H-[1]-benzopyran-8-yl]acetate (2.5 g) was dissolved in acetic acid (35 ml) and to the solution was added 50% sulfulic acid (30 ml). The mixture was relfuxed for 4 hours. The reaction mixture was diluted with water and crystals deposited were filtered off and recrystallized from the mixed solvent of ethyl acetate and methanol to obtain the title compound, yield 68%.

후처리

  1. filtrationdeposited were filtered off
  2. customrecrystallized from the mixed solvent of ethyl acetate and methanol

출처 및 근거

ORD 기록
ord-86bfc59aafc7461d8d9bfb6f89c8fc53
출처 데이터셋
uspto-grants-1990_02
특허 번호
US04904690

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