Ethyl 2-oxocyclohexanecarboxylate → Ethyl 3-bromo-2-oxocyclohexanecarboxylate

반응식

[CH2:1]([O:3][C:4]([CH:6]1[CH2:11][CH2:10][CH2:9][CH2:8][C:7]1=[O:12])=[O:5])[CH3:2].[Br:13]C1CC(C(C)C)CCC1=O>>[CH2:1]([O:3][C:4]([CH:6]1[CH2:11][CH2:10][CH2:9][CH:8]([Br:13])[C:7]1=[O:12])=[O:5])[CH3:2]

참가 물질

반응물 2

HCID 95543Ethyl 2-oxocyclohexanecarboxylate

HCID 627080672-Bromo-4-isopropyl-cyclohexanone

생성물 1

HCID 121765Ethyl 3-bromo-2-oxocyclohexanecarboxylate

실험 절차

The bromination of 2-oxo-cyclohexane carboxylic acid ethyl ester takes place in a manner similar to that described above for the preparation of 2-bromo-4-isopropyl-cyclohexanone. The title compound is reacted as a crude product without further characterization.

출처 및 근거

ORD 기록: ord-37fb364ca93b408f8103ecfca7b9d4ae
출처 데이터셋: uspto-grants-2010_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07727979B2

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