N,N-dibutyl-4-nitroaniline → HCID 11680158, 화합물
반응식
[N+:1]([C:4]1[CH:18]=[CH:17][C:7]([N:8]([CH2:13][CH2:14][CH2:15][CH3:16])[CH2:9][CH2:10][CH2:11][CH3:12])=[CH:6][CH:5]=1)([O-])=O>CO.[Pd]>[CH2:9]([N:8]([CH2:13][CH2:14][CH2:15][CH3:16])[C:7]1[CH:6]=[CH:5][C:4]([NH2:1])=[CH:18][CH:17]=1)[CH2:10][CH2:11][CH3:12]참가 물질
4
실험 절차
To a solution of 4-nitro-N,N-dibutylaniline from Example 40A (1.0 g, 4.0 mmol) in methanol (10 ml) was added palladium 10 wt % on activated carbon (85 mg, 0.08 mmol) under an atmosphere of hydrogen. The reaction mixture was stirred at room temperature for 4 hours and filtered through celite. After solvent were removed under reduced pressure, the titled material was obtained as a white solid, which was used in next step without purification.
후처리
- filtrationfiltered through celite
- customAfter solvent were removed under reduced pressure
출처 및 근거
- ORD 기록
- ord-85d189a85359411399ed03b60f7a19f3
- 출처 데이터셋
- uspto-grants-2006_10
- 특허 번호
- US07115767B2
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