Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Bromooctane → 1-Bromo-4-(4-octoxyphenyl)benzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Bromooctane | HCID 8140 | — |
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 4-Bromo-4'-hydroxybiphenyl | HCID 95093 | — |
| 용매 | Methyl Ethyl Ketone | HCID 6569 | — |
| 생성물 | 1-Bromo-4-(4-octoxyphenyl)benzene | HCID 2801787 | 66% |
반응 단계
A mixture of 4-bromo-4′-hydroxybiphenyl (50.00 g, 0.2008 mol), 1-bromooctane (50.38 g, 0.2610 mol), potassium carbonate (47.11 g, 0.3414 mol) and butanone (500 cm3) was heated under reflux overnight. The cooled mixture was filtered and the solvent removed on a rotary evaporator. The crude solid was recrystallised from ethanol to yield a white crystalline solid (47.30 g, 66%, m.pt. 120° C.).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07118787B2 |
| 출처 데이터셋 | uspto-grants-2006_10 |
| ORD ID | ord-25cd1da99c1943748b340fcf01f82f0e |
| 출처 메모 | uspto-grants-2006_10 |