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Nitrobenzene → HCID 21910026, 화합물

HRID 1245249
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HRID 1245249 반응식
Br[C:2]1[CH:3]=[CH:4][C:5]2[C:6]3[CH:7]=[CH:8][CH:9]=[C:10]4[C:21]=3[C:14]([C:15]3[C:20]=2[C:19]=1[CH:18]=[CH:17][CH:16]=3)=[CH:13][CH:12]=[CH:11]4.[C:22]1([NH:28][C:29]2[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=2)[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1.C(=O)([O-])[O-].[K+].[K+].[N+](C1C=CC=CC=1)([O-])=O>[Cu]>[C:29]1([N:28]([C:22]2[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=2)[C:2]2[CH:3]=[CH:4][C:5]3[C:6]4[CH:7]=[CH:8][CH:9]=[C:10]5[C:21]=4[C:14]([C:15]4[C:20]=3[C:19]=2[CH:18]=[CH:17][CH:16]=4)=[CH:13][CH:12]=[CH:11]5)[CH:30]=[CH:31][CH:32]=[CH:33][CH:34]=1
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 7416NitrobenzeneHCID 11430Potassium CarbonateHCID 11487DiphenylamineHCID 118097033-Bromoperylene

생성물 1

HCID 21910026HCID 21910026, 화합물

시약·촉매·용매 1

HCID 23978Copper촉매

실험 절차

The following compounds were introduced into a vessel: (a) 3-bromoperylene; (b) diphenylamine; (c) potassium carbonate; (d) copper power; and (e) nitrobenzene. Then, the mixture was stirred at 200 degrees centigrade for 40 hours. After reaction has finished, nitrobenzene was removed under a reduced pressure. Then, chlorofom was added to the mixture, and filtered for removing inorganic materials. A filtrate was condensed, and then, impurities were removed by silica gel column chromatography employing ligroin. As a result, there was obtained a target material, 3-diphenylaminoperylene.

후처리

  1. additionThe following compounds were introduced into a vessel
  2. customAfter reaction
  3. customnitrobenzene was removed under a reduced pressure
  4. additionThen, chlorofom was added to the mixture
  5. filtrationfiltered
  6. customfor removing inorganic materials
  7. customcondensed
  8. customimpurities were removed by silica gel column chromatography

출처 및 근거

ORD 기록
ord-97ba8ae649bb40f79a9e2ef6813b29c1
출처 데이터셋
uspto-grants-2006_10
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US07125614B2

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