1-chloro-7-methoxy-4-nitro-10H-acridin-9-one → 1-Chloro-10-methyl-4-nitro-9(10H)-acridinone

HRID 1248842노트

반응식

HRID 1248842 반응식
ClC1C2C(=O)C3C(=CC=C(OC)C=3)NC=2C([N+]([O-])=O)=CC=1.[Cl:22][C:23]1[C:36]2[C:35](=[O:37])[C:34]3[C:29](=[CH:30][CH:31]=[C:32](OC)[CH:33]=3)[N:28]([CH3:40])[C:27]=2[C:26]([N+:41]([O-:43])=[O:42])=[CH:25][CH:24]=1>>[Cl:22][C:23]1[C:36]2[C:35](=[O:37])[C:34]3[C:29](=[CH:30][CH:31]=[CH:32][CH:33]=3)[N:28]([CH3:40])[C:27]=2[C:26]([N+:41]([O-:43])=[O:42])=[CH:25][CH:24]=1

참가 물질

3

반응물 2

HCID 4382311-chloro-7-methoxy-4-nitro-10H-acridin-9-oneHCID 135883401-chloro-7-methoxy 10-methyl-4-nitro-9(10H)-acridinone

생성물 1

HCID 135883211-Chloro-10-methyl-4-nitro-9(10H)-acridinone

실험 절차

In the same manner, 7.62 g (0.025 mol) of 1-chloro-7-methoxy-4-nitro-9(10H)-acridinone was converted to 5.05 g (63%) of 1-chloro-7-methoxy 10-methyl-4-nitro-9(10H)-acridinone, mp 235°-240° C. after recrystallization from toluene.

후처리

  1. customafter recrystallization from toluene

출처 및 근거

ORD 기록
ord-a31ee59560c34fcdb3209244111e69ae
출처 데이터셋
uspto-grants-1986_12
특허 번호
US04626540

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