Isotridecan-1-ol → 1,2,3,4,5-Pentaisotridecyloxycarbonylcyclopentadiene
반응식
[CH3:1][O:2][C:3]([C:5]1[CH:9]([C:10]([O:12][CH3:13])=[O:11])[C:8]([C:14]([O:16][CH3:17])=[O:15])=[C:7]([C:18]([O:20][CH3:21])=[O:19])[C:6]=1[C:22]([O:24][CH3:25])=[O:23])=[O:4].C(O)[CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:38])[CH3:37]>CO>[CH2:25]([O:24][C:22]([C:6]1[CH:5]([C:3]([O:2][CH2:1][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38])=[O:4])[C:9]([C:10]([O:12][CH2:13][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38])=[O:11])=[C:8]([C:14]([O:16][CH2:17][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38])=[O:15])[C:7]=1[C:18]([O:20][CH2:21][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38])=[O:19])=[O:23])[CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38]참가 물질
4
실험 절차
7.13 g (20 mmol) of 1,2,3,4,5-pentamethoxycarbonylcyclopentadiene are treated with 20.0 g (100 mmol) of isotridecyl alcohol. 3.12 g (97.5% of the theoretical yield) of methanol are distilled off at 100° C. within 8 h, firstly at 1013 mbar, then at from 363 to 18 mbar. 24 g of 1,2,3,4,5-pentaisotridecyloxycarbonylcyclopentadiene are obtained.