Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trichlorosilane → 4-Acetoxyphenylethyl trichlorosilane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trichlorosilane | HCID 24811 | — |
| 반응물 | 4-Ethenylphenyl acetate | HCID 75821 | — |
| 촉매 | Platinate(2-), hexachloro-, hydrogen, hydrate (1:2:1), (OC-6-11)- | HCID 16211507 | — |
| 용매 | Heptane | HCID 8900 | — |
| 생성물 | 4-Acetoxyphenylethyl trichlorosilane | HCID 24863406 | — |
반응 단계
Trichlorosilane (56.9 grams, 0.42 mole), 4-acetoxystyrene (64.6 grams, 0.40 mole), and 200 ml heptane were placed in a round bottom flask equipped with a water condenser and nitrogen inlet. Hydrogen hexachloroplatinate(IV) hydrate (20 mg) was added to this solution and heated to reflux for 18 hours. Afterwards, the solution was filtered hot through a frit funnel. The solvent and the unreacted reagents were distilled off at atmospheric pressure and the residue was purified by distillation under reduced pressure. 4-acetoxyphenylethyl trichlorosilane (91.2 grams) was collected between 105-125° C. at 1 mm Hg pressure as a waxy solid.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06340734B1 |
| 출처 데이터셋 | uspto-grants-2002_01 |
| ORD ID | ord-56628456b58d4a5a857acf09f2895dc5 |
| 출처 메모 | uspto-grants-2002_01 |