Ammonia → N-ethyl-4-amino-2-oxo-3-pentenesulfonamide

HRID 1252246노트

반응식

HRID 1252246 반응식
[CH2:1]([N:3]1[C:8]([CH3:9])=[CH:7][C:6](=[O:10])[CH2:5][S:4]1(=[O:12])=[O:11])[CH3:2].[NH3:13]>CO>[CH2:1]([NH:3][S:4]([CH2:5][C:6](=[O:10])[CH:7]=[C:8]([NH2:13])[CH3:9])(=[O:12])=[O:11])[CH3:2]

참가 물질

4

반응물 2

HCID 222AmmoniaHCID 201410202-ethyl-3-methyl-1,2-thiazin-5(6H)-one 1,1-dioxide

생성물 1

HCID 86742149N-ethyl-4-amino-2-oxo-3-pentenesulfonamide

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

A suspension of 13 g of 2-ethyl-3-methyl-1,2-thiazin-5(6H)-one 1,1-dioxide in 130 ml of methanol was reacted with ammonia in accordance with the procedure described in Example 1. The dark yellow solution obtained was concentrated to dryness under reduced pressure and the crystalline residue was recrystallized from ethanol. There were obtained 12.2 g of N-ethyl-4-amino-2-oxo-3-pentenesulfonamide in the form of colorless crystals, m.p. 112°-114°.

후처리

  1. customThe dark yellow solution obtained
  2. concentrationwas concentrated to dryness under reduced pressure
  3. customthe crystalline residue was recrystallized from ethanol

출처 및 근거

ORD 기록
ord-24c2ec5fe40a4c70968c5a5bad14646d
출처 데이터셋
uspto-grants-1988_05
특허 번호
US04742069

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