Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cesium fluoride → Triphenylene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cesium fluoride | HCID 25953 | — |
| 반응물 | Acetonitrile toluene | HCID 21584213 | — |
| 촉매 | palladium(II) acetate | HCID 167845 | — |
| 촉매 | Ferrocene-1,1'-bis-(diphenylphosphine) | HCID 635956 | — |
| 생성물 | Triphenylene | HCID 9170 | — |
반응 단계
1-trifluoromethanesulfonato-2-trimethylsilylbenzene (3 equivalents) is reacted with 1 equivalent of the appropriate iodoaromatic (see scheme 5a), in the presence of 5 mol % of Pd(OAc)2, 5 mol % of dppf and 4 equivalents of CsF in toluene/acetonitrile, to obtain the desired ligands of the formulae IId), IIe) and IIf).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08455112B2 |
| 출처 데이터셋 | uspto-grants-2013_06 |
| ORD ID | ord-dc6baef536d2463899c681964776dcd1 |
| 출처 메모 | uspto-grants-2013_06 |