1-[3-Methoxy-5-(pentafluorosulfanyl)phenyl]ethanone → 1-[3-Bromo-5-(pentafluorosulfanyl)phenyl]ethanone

HRID 1258525노트

반응식

HRID 1258525 반응식
[Br:1][C:2]1[CH:3]=[C:4]([CH:11]=[C:12]([S:14]([F:19])([F:18])([F:17])([F:16])[F:15])[CH:13]=1)[C:5](N(OC)C)=[O:6].[CH3:20]OC1C=C(C(=O)C)C=C(S(F)(F)(F)(F)F)C=1>>[Br:1][C:2]1[CH:3]=[C:4]([C:5](=[O:6])[CH3:20])[CH:11]=[C:12]([S:14]([F:19])([F:18])([F:17])([F:16])[F:15])[CH:13]=1

참가 물질

3

반응물 2

HCID 441831181-[3-Methoxy-5-(pentafluorosulfanyl)phenyl]ethanoneHCID 581374643-Bromo-N-methoxy-N-methyl-5-(pentafluorosulfanyl)benzamide

생성물 1

HCID 581374301-[3-Bromo-5-(pentafluorosulfanyl)phenyl]ethanone

실험 절차

3-Bromo-N-methoxy-N-methyl-5-(pentafluorosulfanyl)benzamide (1.1 g) was converted and worked up analogously to 21d). Purification by means of HPLC was not necessary. 935 mg of the title compound were obtained.

후처리

  1. customPurification by means of HPLC

출처 및 근거

ORD 기록
ord-0638a360c6e0479685fe10f5a85c7df0
출처 데이터셋
uspto-grants-2013_06
특허 번호
US08466169B2

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