Methyl 3-bromobenzoate → Methyl 2-(4-formylphenyl)benzoate

HRID 1264306

반응식

HRID 1264306 반응식
I[C:2]1[CH:11]=[CH:10][CH:9]=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5].Br[C:13]1[CH:14]=[C:15]([CH:20]=[CH:21][CH:22]=1)[C:16](OC)=[O:17]>>[CH3:7][O:6][C:4]([C:3]1[CH:8]=[CH:9][CH:10]=[CH:11][C:2]=1[C:22]1[CH:21]=[CH:20][C:15]([CH:16]=[O:17])=[CH:14][CH:13]=1)=[O:5]

참가 물질

3

반응물 2

HCID 12070Methyl 3-bromobenzoateHCID 69132Benzoic acid, 2-iodo-, methyl ester

생성물 1

HCID 4325150Methyl 2-(4-formylphenyl)benzoate

실험 절차

Using essentially the same procedure used in reference example 97b except using methyl 2-iodo-benzoate as substrate in place of methyl 3-bromo-benzoate. MS (EI) m/z 240 (M)+.

출처 및 근거

ORD 기록
ord-598cc92629254f3c84f030fad8559861
출처 데이터셋
uspto-grants-2003_04
특허 번호
US06541505B1

연결된 노트

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