4-Chlorotoluene → Tris(4-methylphenyl)sulfanium Chloride

반응식

[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=O)=[CH:4][CH:3]=1.[Cl:17][C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=1>>[Cl-:17].[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S+:8]([C:18]2[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=2)[C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=[CH:4][CH:3]=1

참가 물질

반응물 2

HCID 78104-Chlorotoluene

HCID 15680p-Tolyl sulfoxide

생성물 1

HCID 5351245Tris(4-methylphenyl)sulfanium Chloride

실험 절차

The end compound was synthesized as in Synthesis Example 2 except that bis(4-methylphenyl) sulfoxide was used instead of the phenyl sulfoxide in Synthesis Example 2, 4-chlorotoluene was used instead of the chlorobenzene, and the quantity of water for extraction was increased.

후처리

extractionthe quantity of water for extraction
temperaturewas increased

출처 및 근거

ORD 기록: ord-2ab54aa1700d4413a21cc07af36731d8
출처 데이터셋: uspto-grants-2003_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06551758B2

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