HCID 600649, 화합물 → HCID 178506818, 화합물
반응식
[CH3:1][O:2][C:3]1[CH:4]=[C:5]2[C:9](=[CH:10][C:11]=1[O:12][CH3:13])[CH2:8][CH:7]=[CH:6]2.[Li:14]CCCC>C1(C)C=CC=CC=1.CCCCCC>[CH3:13][O:12][C:11]1[CH:10]=[C:9]2[C:5](=[CH:4][C:3]=1[O:2][CH3:1])[CH:6]([Li:14])[CH:7]=[CH:8]2참가 물질
5
실험 절차
5,6-Dimethoxy-indene (4.82 g, 27.35 mmol) was dissolved in a mixture of 20 mL of toluene and 180 mL of hexane and 16.25 mL of 1.6 M n-BuLi were added dropwise via a syringe over a 5 min period forming a white precipitate. The reaction mixture was stirred for 4 h then filtered. The solids were washed with 60 mL of hexane and allowed to dry under reduced pressure to afford the desired anion as a light pink solid (4.62 g, 98 percent yield).
후처리
- additionwere added dropwise via a syringe over a 5 min period
- customforming a white precipitate
- filtrationthen filtered
- washThe solids were washed with 60 mL of hexane
- customto dry under reduced pressure
출처 및 근거
- ORD 기록
- ord-eb8f128bb6ef4713ad10aa97dccdf63d
- 출처 데이터셋
- uspto-grants-2003_04
- 특허 번호
- US06555634B1
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