Ethyl Acetate → 4-Benzoyloxy-1-octyne

HRID 127058노트

반응식

[OH:1][CH:2]([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:3][C:4]#[CH:5].C([O:13][CH2:14][CH3:15])(=O)C>>[C:14]([O:1][CH:2]([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:3][C:4]#[CH:5])(=[O:13])[C:15]1[CH:7]=[CH:6][CH:2]=[CH:3][CH:4]=1

참가 물질

반응물 2

HCID 8857Ethyl Acetate

HCID 1036561-Octyn-4-ol

생성물 1

HCID 204420544-Benzoyloxy-1-octyne

실험 절차

From fractions 13-20 is obtained 75 mg of colorless oil, identical to 4-hydroxy-1-octyne, [α]D25 =-17°±1.0° (C=0.77, ethyl acetate). This compound has the (R)-configuration.

출처 및 근거

ORD 기록: ord-92cd3081adf34c7dacc0cab9bb30869d
출처 데이터셋: uspto-grants-1981_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04254285

반응 노트

불러오는 중…