참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Tricyclohexylphosphine | HCID 75806 | — |
| 반응물 | Bicyclo[2.2.1]hept-2-ene, 5-butyl- | HCID 168020 | — |
| 반응물 | N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate | HCID 10996402 | — |
| 반응물 | Butyl bicyclo[2.2.1]hept-5-ene-2-carboxylate | HCID 15608148 | — |
| 촉매 | palladium(II) acetate | HCID 167845 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 5-Butylnorbornene 5-norbornene-2-carboxylic acid butyl ester | HCID 86600018 | — |
반응 단계
5-Butylnorbornene (730 g) and 5-norbornene-2-carboxylic acid butyl ester (940 g) were added to a reactor at room temperature. Then, toluene (1,600 g) was added to the reactor. The air inside the reactor was replaced by nitrogen and the reactor was heated to 90° C. Then, palladium diacetate (0.21 g), dimethyl aniliniumtetrakis (pentafluorophenyl)borate (1.55 g) and tricylcohexylphosphine (0.27 g) dissolved in dichloromethyl were added to the reactor. Reaction was performed for 18 hours while stirring to obtain a polymer solution.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07202312B2 |
|---|
| 출처 데이터셋 | uspto-grants-2007_04 |
|---|
| ORD ID | ord-45f737c0c5824ce1a33c22ee2566cec1 |
|---|
| 출처 메모 | uspto-grants-2007_04 |
|---|
