Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4,4'-Bis(dimethylamino)diphenylamine → 3-[4-(Diethylamino)-2-methylphenyl]-3-{bis[4-(dimethylamino)phenyl]amino}phthalide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4,4'-Bis(dimethylamino)diphenylamine | HCID 69473 | — |
| 반응물 | 2-(4-(Diethylamino)-2-methylbenzoyl)benzoic acid | HCID 104335 | — |
| 생성물 | 3-[4-(Diethylamino)-2-methylphenyl]-3-{bis[4-(dimethylamino)phenyl]amino}phthalide | HCID 15519333 | 54% |
반응 단계
Following a procedure similar to that described in Example 4 but employing 3.1 g of 2-[4-(diethylamino)-2-methylbenzoyl]benzoic acid and 3.0 g of 4,4'-bis(dimethylamino)diphenylamine there was obtained 2.95 g of 3-[4-(diethylamino)-2-methylphenyl]-3-{bis[4-(dimethylamino)phenyl]amino}phthalide, m.p. 67°-83° C. A toluene solution of the product contacted with acidic clay or phenolic resin developed a black-colored image.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04255577 |
| 출처 데이터셋 | uspto-grants-1981_03 |
| ORD ID | ord-addf0cc382fb4746827f1a64f5e57980 |
| 출처 메모 | uspto-grants-1981_03 |