Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sulfuric acid magnesium salt (1:1) → Methyl (2E)-{[(2,4-dimethoxyphenyl)methyl]imino}acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sulfuric acid magnesium salt (1:1) | HCID 24083 | — |
| 반응물 | Acetic acid, 2-oxo-, methyl ester | HCID 70205 | — |
| 반응물 | 2,4-Dimethoxybenzylamine | HCID 597250 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Methyl (2E)-{[(2,4-dimethoxyphenyl)methyl]imino}acetate | HCID 23470137 | — |
반응 단계
To a mixture containing 16.82 g (0.101 mole) of 2,4-dimethoxybenzylamine and anhydrous magnesium sulfate in 150 ml of methylene chloride at 25° is added a solution of 10.05 g (0.114 mole) of methyl glyoxalate in 20 ml of methylene chloride. The reaction mixture is stirred at room temperature overnight (15 hours) and then is filtered and the solvents are removed in vacuo to afford the imine as a dark orange gum.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04257947 |
| 출처 데이터셋 | uspto-grants-1981_03 |
| ORD ID | ord-3a6afd3455a641c0957d904292864f54 |
| 출처 메모 | uspto-grants-1981_03 |