1H-Cyclopenta[l]phenanthrene → 2,3-Dihydro-1H-cyclopenta[l]phenanthrene

HRID 1279672노트

반응식

HRID 1279672 반응식
[CH2:1]1[C:5]2[C:6]3[C:11]([C:12]4[CH:13]=[CH:14][CH:15]=[CH:16][C:17]=4[C:4]=2[CH:3]=[CH:2]1)=[CH:10][CH:9]=[CH:8][CH:7]=3.[H][H]>[Pd].C1(C)C=CC=CC=1>[CH2:3]1[C:4]2[C:17]3[C:12]([C:11]4[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=4[C:5]=2[CH2:1][CH2:2]1)=[CH:13][CH:14]=[CH:15][CH:16]=3

참가 물질

5

반응물 2

HCID 118061071H-Cyclopenta[l]phenanthreneHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 6128122,3-Dihydro-1H-cyclopenta[l]phenanthrene

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 1140Toluene용매

실험 절차

A mixture of 2 g cyclopentaphenanthrene, 0.2 g 10% palladium on carbon and 50 mL toluene was stirred under hydrogen (69 kPa) until hydrogen uptake ceased, about 48 h. Catalyst was removed by filtration through diatomaceous earth and the filtrate evaporated. The crude product remaining weighed 1.97 g. It was further purified by recrystallization from heptane at −40° C. to give 1.8 g colorless plates. Spectroscopic and chemical analysis confirmed the identity of the desired compound.

후처리

  1. customCatalyst was removed by filtration through diatomaceous earth
  2. customthe filtrate evaporated
  3. customIt was further purified by recrystallization from heptane at −40° C.
  4. customto give 1.8 g colorless plates

출처 및 근거

ORD 기록
ord-19e147d26f284bde827d5b5af2a3eb28
출처 데이터셋
uspto-grants-2002_09
특허 번호
US06448358B2

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