Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Bromo-4-(bromomethyl)benzenemethanol → 2-Bromo-4-(bromomethyl)benzaldehyde
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Bromo-4-(bromomethyl)benzenemethanol | HCID 12016037 | — |
| 촉매 | Manganese dioxide | HCID 14801 | — |
| 용매 | Ethanol ethylacetate | HCID 21584252 | — |
| 생성물 | 2-Bromo-4-(bromomethyl)benzaldehyde | HCID 12016038 | 80.6% |
반응 단계
The compound of Step 2 (8 g, 29 mmol, 1 eq) was dissolved in 10% EtOH/EtOAc (300 ml) and 5 eq of MnO2 (12.4 g, 142 mmol) was added every hour for 6 hours. The mixture was filtered through Celite and the solvent was removed under vacuum to give 6.5 g (80%) of the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06448429B1 |
| 출처 데이터셋 | uspto-grants-2002_09 |
| ORD ID | ord-73d50750a02541589a348a788318e6aa |
| 출처 메모 | uspto-grants-2002_09 |