Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Myrcene → (Z)-2,6-dimethyloct-2-ene-1,8-diol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Myrcene | HCID 31253 | — |
| 반응물 | Sodium Acetate | HCID 517045 | — |
| 반응물 | Neryl acetate | HCID 1549025 | — |
| 반응물 | Calcium Hydroxide | HCID 6093208 | — |
| 반응물 | Dichloro di-methyloctene | HCID 20571628 | — |
| 용매 | Benzene | HCID 241 | — |
| 용매 | Triethylamine | HCID 8471 | — |
| 생성물 | (Z)-2,6-dimethyloct-2-ene-1,8-diol | HCID 77134639 | — |
반응 단계
Prod.: (many methods) e.g. from Myrcene, via Myrcene dihydrochloride to Dichloro di-methyloctene. This is converted to Chloro di-hydrogeranyl acetate (and-neryl acetate) with Sodium Acetate in Benzene in presence of Triethylamine. The acetates are saponified with Calcium hydroxide to yield Hydroxycitronellol, from which the aldehyde is prepared by oxidation.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04258727 |
| 출처 데이터셋 | uspto-grants-1981_03 |
| ORD ID | ord-556bbc3a328e454ab039bc372f2aeabf |
| 출처 메모 | uspto-grants-1981_03 |