Allyl Isothiocyanate → HCID 21519702, 화합물
반응식
[C:1]([C:5]1[CH2:6][CH2:7][NH:8][CH2:9][CH:10]=1)([CH3:4])([CH3:3])[CH3:2].[CH2:11]([N:14]=[C:15]=[S:16])[CH:12]=[CH2:13]>O1CCCC1>[CH2:11]([NH:14][C:15]([N:8]1[CH2:7][CH:6]=[C:5]([C:1]([CH3:4])([CH3:3])[CH3:2])[CH2:10][CH2:9]1)=[S:16])[CH:12]=[CH2:13]참가 물질
4
실험 절차
In 20 ml. of anhydrous tetrahydrofuran there is dissolved 5.0 grams of 4-t-butyl-1,2,3,6-tetrahydropyridine, and with stirring there is added 3.5 grams of allylisothiocyanate in 10 ml of anhydrous tetrahydrofuran. The reaction mixture is stirred for 24 hours at room temperature and the tetrahydrofuran is evaporated in vacuo. The resulting solid is dried at 50°C/20 mmHg. to remove any unreacted allylisothiocyanate to give N-allyl-4-t-butyl-1,2,3,6- -tetrahydro-1-pyridinethiocarboxamide.
후처리
- stirringThe reaction mixture is stirred for 24 hours at room temperature
- customthe tetrahydrofuran is evaporated in vacuo
- customThe resulting solid is dried at 50°C/20 mmHg
- customto remove any unreacted allylisothiocyanate
출처 및 근거
- ORD 기록
- ord-156cd34da4c54483b673ae5ca938c41d
- 출처 데이터셋
- uspto-grants-1976_08
- 특허 번호
- US03974283
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