Nitric Acid → 2-Nitro-5-phenyl indane-1,3-dione

HRID 1284311

반응식

[C:1]1([C:7]2[CH:8]=[C:9]3[C:13](=[CH:14][CH:15]=2)[C:12](=[O:16])[CH2:11][C:10]3=[O:17])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[N+:18]([O-])([OH:20])=[O:19]>>[N+:18]([CH:11]1[C:10](=[O:17])[C:9]2[C:13](=[CH:14][CH:15]=[C:7]([C:1]3[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=3)[CH:8]=2)[C:12]1=[O:16])([O-:20])=[O:19]

참가 물질

반응물 2

HCID 944Nitric Acid

HCID 223458365-Phenyl indane-1,3-dione

생성물 1

HCID 215030642-Nitro-5-phenyl indane-1,3-dione

실험 절차

Nitration of 5-phenyl indane-1,3-dione with fuming nitric acid as described in Example 16 (c) gave 2-nitro-5-phenyl indane-1,3-dione, m.p. (water, hydrochloric acid) 119°C. (Found: C, 65.54; H, 3.39; N, 4.93; C15H9NO4. 1/2 H2O requires: C, 65.21; H, 3.65; N, 5.07%).

출처 및 근거

ORD 기록: ord-d50de67e417d4d438efcc29ca6f58dcc
출처 데이터셋: uspto-grants-1976_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US03978231

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